About this calculator
Psychrometrics is the study of moist air — the mixture of dry air and water vapour that air-conditioning systems heat, cool, humidify and dehumidify. From the dry-bulb temperature, the relative humidity and the air pressure, this calculator finds the other properties you would read from a psychrometric chart: humidity ratio, dew point, wet-bulb temperature, enthalpy, specific volume and density.
Unlike a printed chart, it works at any altitude or pressure, which matters for sites well above sea level.
Formula
pw = RH × pws(t) W = 0.621945 × pw ÷ (p − pw)
h = 1.006 t + W (2501 + 1.86 t) kJ/kg dry air
v = 0.287042 (t + 273.15)(1 + 1.607858 W) ÷ p m³/kg dry air (p in kPa)
pws = saturation pressure of water vapour, from the Hyland–Wexler equations (over ice at or below 0.01 °C, over liquid water above), valid from −100 °C to +200 °C. Dew point: the temperature td at which pws(td) = pw. Wet bulb t*: solved from the ASHRAE energy balance below (with the ice-bulb form below 0 °C), where Ws* is the saturation humidity ratio at t*.
W = [(2501 − 2.326 t*) Ws* − 1.006 (t − t*)] ÷ (2501 + 1.86 t − 4.186 t*)
Pressure from altitude Z (m), standard atmosphere:
p = 101.325 (1 − 2.25577 × 10⁻⁵ Z)5.2559 kPa
The SI enthalpy is zero for dry air at 0 °C. The inch-pound enthalpy, h = 0.240 t + W (1061 + 0.444 t) Btu/lb with t in °F, is zero for dry air at 0 °F, so the two values are not a simple unit conversion of each other. Enthalpy differences do convert directly: 1 Btu/lb = 2.326 kJ/kg.
Worked example
- Air at 30 °C and 50% RH at sea level (101.325 kPa): pws = 4.246 kPa, pw = 2.123 kPa, W = 0.621945 × 2.123 ÷ (101.325 − 2.123) = 13.3 g/kg; dew point 18.4 °C; wet bulb 22.0 °C; h = 1.006 × 30 + 0.01331 × (2501 + 1.86 × 30) = 64.2 kJ/kg; v = 0.877 m³/kg.
- The same air at 1500 m altitude (84.6 kPa) has a higher humidity ratio, 16.0 g/kg, because the same vapour pressure is mixed with less dry air.
Assumptions and limitations
- Moist air is treated as a mixture of ideal gases (the standard ASHRAE method). This is accurate for normal HVAC conditions; above about 90 °C, or at high pressure, results are approximate.
- Valid ranges: dry bulb −100 °C to +200 °C; relative humidity above 0% up to 100%; pressure 20 kPa to 120 kPa; altitude −500 m to 11 000 m. Inputs outside these ranges are rejected.
- At or below 0.01 °C, saturation is over ice. Relative humidity and dew point are then relative to ice; many weather reports use relative humidity over water.
- The wet-bulb temperature is the thermodynamic (adiabatic saturation) wet bulb. It is not given when the dry bulb is above the boiling point of water at the given pressure. A sling or aspirated psychrometer reads very close to it; an unventilated wet bulb reads higher.
- Altitude is converted to pressure with the standard atmosphere. Real barometric pressure changes with the weather by a few percent; enter it directly if you know it.
References
- ASHRAE Handbook — Fundamentals, chapter “Psychrometrics” (Hyland–Wexler saturation pressure, humidity ratio, enthalpy, specific volume, wet-bulb equations, standard atmosphere).
- Hyland, R. W. and Wexler, A. (1983), Formulations for the thermodynamic properties of the saturated phases of H₂O from 173.15 K to 473.15 K, ASHRAE Transactions 89(2A).
